Undoped and V-doped 6H—SiC single crystals
have been grown by the physical vapor transport method. The V concentration is
determined to be 3.76 × 1017 at/cm3 and 6.14 × 1017 at/cm3 by secondary ion
mass spectrometry for low V-doped and high V-doped SiC samples, respectively.
The undoped 6H—SiC shows diamagnetism, while the V-doped 6H—SiC exhibits weak
ferromagnetism. The lower V-doped sample shows stronger ferromagnetism compared
to that of the higher V-doped sample. However, the structural characterization
indicates that the lower V-doped SiC has a relative poor crystalline quality.
It is found that both V dopants and defects are essential for introducing
ferromagnetic exchange in V-doped SiC single crystals.
Source:IOPscience
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