Periodically twinned 6H-SiC nanowires with fluctuating stems
were successfully synthesized on SiC substrate by chemical vapor deposition
with ferrocene as the catalyst. The morphology and structures of the products
were systematically characterized by X-ray diffraction, scanning electron
microscopy, and transmission electron microscopy. The results showed that the
nanowires consisted of periodically twinned segments and presented
stem-fluctuating morphology, whose diameters fluctuated in the range of 10–150 nm
along the axial direction. A model based on vapor–liquid–solid mechanism was
proposed to explain the growth of periodically twinned SiC nanowires with
fluctuating stems, which revealed that the alternating high-density stacking
faults facilitated the formation of stem-fluctuating morphology.
Source:Ceramics
International
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